Hydrogen storage in molecular Mg-hydride clusters

Molecular models can help understanding the mechanisms and show that smaller cluster size leads to lower H2 desorption temperatures.

Angew. Chem., Int. Ed. 2017, 56, 5021
Self-​Assembly of Magnesium Hydride Clusters Driven by Chameleon-​Type Ligands
DOI: Angew. Chem. Int. Ed.10.1002/anie.201700719

Angew. Chem., Int. Ed. 2011, 50, 4156
Hydrogen Storage in Magnesium Hydride: The Molecular Approach
DOI: Angew. Chem. Int. Ed.10.1002/anie.201101153

Chem. Eur. J. 2013, 19, 8478
Well-Defined Molecular Magnesium Hydride Clusters:
Relationship between Size and Hydrogen Elimination Temperature
DOI: 10.1002/chem.201300684